The Michael T. Crimmins Group Home Page


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Methodology

52. "Synthesis of Crossed [2 + 2] Photocycloadducts: A Novel Approach to the Synthesis of Bridged Bicyclic Alkenes" Crimmins, M. T.; Hauser, E. B. Org. Lett. 2000, 2, 281-284.
| Full Article-PDF | DOI: 10.1021/ol991272d |

40. "Synthesis and Intramolecular Photocycloadditions of 2-Acyloxy-3-Hexenoyl Cyclohexenones: Diastereoselectivity in the Intramolecular [2 + 2] Photocycloadditions of Alkenes and Cyclohexenones Tethered by Four Atoms" Crimmins, M. T.; Watson, P. S.; King, B. W.; Guise, L. E. Tetrahedron 1997, 53, 8963-8974.
| Full Article-PDF | DOI: 10.1016/S0040-4020(97)90403-8 |

38. "Solvent Effects on Diastereoselective Intramolecular [2 + 2] Photocycloadditions: Reversal of Selectivity through Intramolecular Hydrogen Bonding" Crimmins, M. T.; Choy, A. L. J. Am. Chem. Soc. 1997, 119, 10237-10238.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja9717119 |

31. "Rearrangement of Cyclobutylcarbinyl Radicals. The Total Synthesis of the Spirovetivane Phytoalexin, (±)-Lubiminol" Crimmins, M. T.; Wang, Z.; McKerlie, L. A. Tetrahedron Lett. 1996, 37, 8703-8706.
| Full Article-PDF | DOI: 10.1016/S0040-4039(96)02020-5 |

29. "Siloxanes as Temporary Tethers in [2 + 2] Photocycloadditions" Crimmins, M. T.; Guise, L. E. Tetrahedron Lett. 1994, 35, 1657-1660.
| Full Article-PDF | DOI: 10.1016/0040-4039(94)88312-2 |

Reviews

28. "Enone Olefin [2 + 2] Photochemical Cycloadditions" Crimmins, M. T.; Renihold, T. L. Organic Reactions 1993, 44, 297-588.
| DOI: 10.1002/0471264180.or044.02 |

14. "Synthetic Applications of Intramolecular Enone-Olefin Photocycloadditions" Crimmins, M. T. Chem. Rev. 1988, 88, 1453-1473.
| Full Article-PDF | DOI: 10.1021/cr00090a002 |

Examples in Synthesis

60. "Total Synthesis of (±)-Ginkgolide B" Crimmins, M. T; Pace, J. M.; Nantermet, P. G.; Kim-Meade, A. S.; Thomas, J. B.; Watterson, S. H.; Wagman, A. S. J. Am. Chem. Soc. 1999, 121, 10249-10250.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja993013p |

41. "Double Diastereoselection in Intramolecular Photocycloadditions: A Radical Rearrangement Approach to the Total Synthesis of the Spirovetivane Phytoalexin (±)-Lubiminol" Crimmins, M. T.; Wang, Z.; McKerlie, L. A. J. Am. Chem. Soc. 1998, 120, 1747-1756.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja973824y |

31. "Rearrangement of Cyclobutylcarbinyl Radicals. The Total Synthesis of the Spirovetivane Phytoalexin, (±)-Lubiminol" Crimmins, M. T.; Wang, Z.; McKerlie, L. A. Tetrahedron Lett. 1996, 37, 8703-8706.
| Full Article-PDF | DOI: 10.1016/S0040-4039(96)02020-5 |

24. "Stereoselective Intramolecular Enone-Olefin Photocycloadditions of 1,7-Dienes: Model Studies on the Synthesis of Lycopodium Alkaloids" Crimmins, M. T.; Watson, P. S. Tetrahedron Lett. 1993, 34, 199-202.
| Full Article-PDF | DOI: 10.1016/S0040-4039(00)60546-4 |

14. "Synthetic Applications of Intramolecular Enone-Olefin Photocycloadditions" Crimmins, M. T. Chem. Rev. 1988, 88, 1453-1473.
| Full Article-PDF | DOI: 10.1021/cr00090a002 |

12. "Intramolecular Photocycloaddition-Cyclobutane Fragmentation: Total Synthesis of (±)-Laurenene" Crimmins, M. T.; Bredon, L. D. J. Am. Chem Soc. 1987, 109, 6199.
| Full Article-PDF | DOI: 10.1021/ja00254a058 |

8. "Intramolecular Photocycloadditions-Cyclobutane Fragmentation: Total Synthesis of (±)-Pentalenene, (±)-Pentalenic Acid, and (±)-Deoxypentalenic Acid" Crimmins, M. T.; DeLoach, J. A. J. Am. Chem. Soc. 1986, 108, 800.
| Full Article-PDF | DOI: 10.1021/ja00264a037 |

7. "Intramolecular Photocycloadditions-Cyclobutane Fragmentation: Total Synthesis of (±)-Silphinene" Crimmins, M. T.; Mascarella, S. W. J. Am. Chem. Soc. 1986, 108, 3435.
| Full Article-PDF | DOI: 10.1021/ja00272a044 |

5. "Intramolecular Photocycloadditions: Synthesis of Sterically Congested Substituted [4.5.5.5] Fenestranes. Models for the Total Synthesis of Laurenene and Silphinene" Crimmins, M. T.; Mascarella, S. W.; Bredon, L. D. Tetrahedron Lett. 1985, 26, 997-1000.
| Full Article-PDF | DOI: 10.1016/S0040-4039(00)98495-8 |

3. "Intramolecular Photocycloaddition-cyclobutane Fragmentation: A Highly Stereoselective Total Synthesis of (±)-Pentalenic Acid" Crimmins, M. T.; DeLoach, J. A. J. Org. Chem. 1984, 49, 2076-2077.
| Full Article-PDF | DOI: 10.1021/jo00185a069 |