The Michael T. Crimmins Group Home Page


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2010

107. "Total Synthesis of the Proposed Structure of Briarellin J" Michael T. Crimmins; Mark C. Mans; Abimael D. Rodriguez Org. Lett. 2010, 12, 5028-5031.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol102169w|

106. "Enantioselective Total Synthesis of Spirofungins A and B" Michael T. Crimmins; Elizabeth A. O'Bryan Org. Lett. 2010, 12, 4416-4419.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol1015898|

105. "Synthesis of the Bis-tetrahydropyran Core of Amphidinol 3" Michael T. Crimmins; Timothy J. Martin Org. Lett. 2010, 12, 3890-3893.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol101961c|

104. "A Highly Convergent Approach toward (-)-Brevenal" Crimmins, M. T.; Shamszad, M.; Mattson, A. E. Org. Lett. 2010, 12, 2614-2617.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol1008203 |

2009

103. "Total Synthesis of Irciniastatin A (Psymberin)" Crimmins, M. T.; Stevens, J. M.; Schaaf, G. M. Org. Lett. 2009, 11, 3990-3993.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol901655e |

102. "Enantioselective Total Synthesis of Brevetoxin A: Convergent Coupling Strategy and Completion" Crimmins, M. T.; Zuccarello, J. L.; McDougall, P. J.; Ellis, J. M. Chem. Eur. J. 2009, 15, 9235-9244.
| Full Article-PDF | (Supporting Information) | DOI: 10.1002/chem.200900777 |

101. "Enantioselective Total Synthesis of Brevetoxin A: Unified Strategy for the B, E, G, and J Subunits" Crimmins, M. T.; Ellis, J. M.; Emmitte, K. A.; Haile, P. A.; McDougall, P. J.; Parrish, J. D.; Zuccarello, J. L. Chem. Eur. J. 2009, 15, 9223-9234.
| Full Article-PDF | (Supporting Information) | DOI: 10.1002/chem.200900776 |

100. "Asymmetric Total Synthesis of Pyranicin" Crimmins, M. T.; Jacobs, D. L. Org. Lett. 2009, 11, 2695-2698.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol900814w |

99. "Enantioselective Total Synthesis of (-)-Pironetin: Iterative Aldol Reactions of Thiazolidinethiones" Crimmins, M. T.; Dechert, A.-M. R. Org. Lett. 2009, 11, 1635-1638.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol9003228 |

98. "Total Synthesis of Apoptolidin A" Crimmins, M. T.; Christie, H. S.; Long, A.; and Chaudhary, K. Org. Lett. 2009, 11, 831-834.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol802829n |

97. "Total Synthesis of Brevetoxin A" Crimmins, M. T.; Zuccarello, J. L.; Ellis, J. M.; McDougall, P. J.; Haile, P. A.; Parrish, J. D.; Emmitte, K. A. Org. Lett. 2009, 11, 489-492.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol802710u |

2008

96. "Strategies for the Total Synthesis of C2-C11 Cyclized Cembranoids" Ellis, J. M.; Crimmins, M. T. Chem. Rev. 2008, 108, 5278-5298.
| Full Article-PDF | DOI: 10.1021/cr078117u |

JOC Cover Article 95. "An Intramolecular Diels-Alder Strategy for the Asbestinins: Enantioselective Total Syntheses of 11-Acetoxy-4-deoxyasbestinin D and Asbestinin-12" Crimmins, M. T.; Ellis, J. M. J. Org. Chem. 2008, 73, 1649-1660.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/jo0712695 |

2007

94. "Highly Selective Acetate Aldol Additions Using Mesityl-Substituted Chiral Auxiliaries" Crimmins, M. T.; Shamszad, M. J. Org. Chem. 2007, 9, 149-152.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol062688b |

2006

93. "Synthesis of the C29-C37 Bicyclic Ether Core of (+)-Sorangicin A" Crimmins, M. T.; Haley, M. W. Org. Lett. 2006, 8, 4223-4225.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol061339e |

92. "Improved Synthesis of the ABCDE Fragment of Brevetoxin A" Crimmins, M. T.; McDougall, P. J.; Ellis, J. M. Org. Lett. 2006, 8, 4079-4082.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol0615782 |

91. "Enantioselective Total Synthesis of (+)-SCH 351448" Crimmins, M. T.; Vanier, G. S. Org. Lett. 2006, 8, 2887-2890.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol061073b |

90. "Total Synthesis of (-)-Mucocin" Crimmins, M. T.; Zhang, Y.; Diaz, F. A. Org. Lett. 2006, 8, 2369-2372.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol060704z |

89. "Formal Synthesis of 6-Deoxyerythronolide B" Crimmins, M. T.; Slade, D. J. Org. Lett. 2006, 8, 2191-2194.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol0607241 |

88. "Enantioselective Total Synthesis of Bistramide A" Crimmins, M. T.; DeBaillie, A. C. J. Am. Chem. Soc. 2006, 128, 4936-4937.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja057686l |

87. "Enantioselective Total Synthesis of FD-891" Crimmins, M. T.; Caussanel, F. J. Am. Chem. Soc. 2006, 128, 3128-3129.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja060018v |

86. "A Hetero-Diels-Alder Approach to Complex Pyrones: An Improved Synthesis of the Spongistatin AB Spiroketal" Crimmins, M. T.; Smith, A. C. Org. Lett. 2006, 8, 1003-1006.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol0601601 |

85. "An Intramolecular Diels-Alder Approach to the Eunicellins: Enantioselective Total Syntheses of Ophirin B and Astrogorgin" Crimmins, M. T.; Brown, B. H.; Plake, H. R. J. Am. Chem. Soc. 2006, 128, 1371-1378.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja056334b |

84. "Convergent, Stereoselective Synthesis of the GHIJ Fragment of Brevetoxin A" Crimmins, M. T.; Zuccarello, J. L.; Cleary, P. A.; Parrish, J. D. Org. Lett. 2006, 8, 159-162.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol0526625 |

2005

83. "Establishing the Absolute Configuration of the Asbestinins: Enantioselective Total Synthesis of 11-Acetoxy-4-deoxyasbestinin D" Crimmins, M. T.; Ellis, J. M. J. Am. Chem. Soc. 2005, 127, 17200-17201.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja056921x |

82. "Enantioselective Synthesis of Apoptolidinone: Exploiting the Versatility of Thiazolidinethione Chiral Auxiliaries" Crimmins, M. T.; Christie, H. S.; Chaudhary, K.; Long, A. J. Am. Chem. Soc. 2005, 127, 13810-13812.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja0549289 |

81. "Enantioselective Synthesis of Apoptolidin Sugars" Crimmins, M. T.; Long, A. Org. Lett. 2005, 7, 4157-4160.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol0515107 |

80. "A Convergent Coupling Strategy for the Formation of Polycyclic Ethers: Stereoselective Synthesis of the BCDE Fragment of Brevetoxin A" Crimmins, M. T.; McDougall, P. J.; Emmitte, K. A. Org. Lett. 2005, 7, 4033-4036.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol051543m |

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2004

79. "Enantioselective Total Synthesis of (+)-Gigantecin: Exploiting the Asymmetric Glycolate Aldol Reaction" Crimmins, M. T.; She, J. J. Am. Chem. Soc. 2004, 126, 12790-12791.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja0455852 |

78. "An Intramolecular Diels-Alder Approach to the Eunicelins: Enantioselective Total Synthesis of Ophirin B" Crimmins, M. T.; Brown, B. H. J. Am. Chem. Soc. 2004, 126, 10264-10266.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja046574b |

77. "An Improved Procedure For Asymmetric Aldol Additions With N-Acyl Oxazolidinones, Oxazolidinethiones, and Thiazolidinethiones" Crimmins, M. T.; She, J. Synlett 2004, 8, 1371-1374.
| Full Article-PDF | DOI: 10.1055/s-2004-825626 |

76. "A Unified Approach to the Enantioselective Synthesis of 2,6-cis- and trans-Disubstituted Tetrahydropyranones" Crimmins, M. T.; Diaz, C. J.; Emmitte, K. A. Heterocycles 2004, 62, 179-183.
| DOI: 10.3987/COM-03-S(P)33 |

2003

75. "Enantioselective Synthesis of the G-Ring of Brevetoxin A" Crimmins, M. T.; Cleary, P. A. Heterocycles 2003, 61, 87-92.
| DOI: 10.3987/COM-03-S46 |

74. "Enantioselective Total Synthesis of (+)-Leucascandrolide A Macrolactone" Crimmins, M. T.; Siliphaivanh, P. Org. Lett. 2003, 5, 4641-4644.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol035797o |

73. "Enantioselective Total Synthesis of (+)-Rogioloxepane A" Crimmins, M. T.; DeBaillie, A. C. Org. Lett. 2003, 5, 3009-3011.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol034923l |

72. "Enantioselective Total Synthesis of (+)-Obtusenyne" Crimmins, M. T.; Powell, M. T. J. Am. Chem. Soc. 2003, 125, 7592-7595.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja029956v |

71. "Anti-Selective Aldol Reactions with Titanium Enolates of N-Glycolyloxazolidinethiones" Crimmins, M. T.; McDougall, P. J. Org. Lett. 2003, 5, 591-594.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol034001i |

2002

70. "Asymmetric Total Synthesis of (-)-Laulimalide: Exploiting the Asymmetric Glycolate Alkylation Reaction" Crimmins, M. T.; Stanton, M. G.; Allwein, S. P. J. Am. Chem. Soc. 2002, 124, 5958-5959.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja026269v |

69. "Asymmetric Total Synthesis of Spongistatins 1 and 2" Crimmins, M. T.; Katz, J. D.; Washburn, D. G.; Allwein, S. P.; McAtee, L. F. J. Am. Chem. Soc. 2002, 124, 5661-5663.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja0262683 |

68. "Ring Closing Metathesis for the Formation of Medium Ring Ethers: The Total Synthesis of (-)-Isolaurallene" Crimmins, M. T.; Emmitte, K. A.; Choy, A. L. Tetrahedron 2002, 58, 1817-1834.
| Full Article-PDF | DOI: 10.1016/S0040-4020(02)00040-6 |

67. "Synthetic Approaches to the Microtubule Stabilizing Agent (-)-Laulimalide" Crimmins, M. T. Curr. Opin. Drug Disc. & Devel. 2002, 5, 944-959.
| Full Article-PDF | Abstract |

66. "Regioselectivity in the Palladium-Catalyzed Addition of Carbon Nucleophiles to Carbocyclic Derivatives" Hoke, M. E.; Brescia, M.-R.; Bogaczyk, S.; DeShong, P.; King, B. W.; Crimmins, M. T. J. Org. Chem. 2002, 67, 327-335.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/jo010672n |

2001

65. "Formal Total Synthesis of (+)-Trehazolin. Application of an Asymmetric Aldol-Olefin Metathesis Approach to the Synthesis of Functionalized Cyclopentenes" Crimmins, M. T.; Tabet, E. A. J. Org. Chem. 2001, 66, 4012-4018.
| Full Article-PDF | DOI: 10.1021/jo015568k |

64. "An Aldol Approach to the Synthesis of the EF Fragment of Spongistatin 1" Crimmins, M. T.; Katz, J. D.; McAtee, L. C.; Tabet, E. A.; Kirincich, S. J. Org. Lett. 2001, 3, 949-952.
| Full Article-PDF | DOI: 10.1021/ol015652m |

63. "Asymmetric Total Synthesis of (-)-Isolaurallene" Crimmins, M. T.; Emmitte, K. A. J. Am. Chem. Soc. 2001, 123, 1533-1534.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja005892h |

62. "Asymmetric Aldol Additions: Use of Titanium Tetrachloride and (-)-Sparteine for the Soft Enolization of N-Acyl Oxazolidinones, Oxazolidinethiones, and Thiazolidinethiones" Crimmins, M. T.; King, B. W.; Tabet, E. A.; Chaudhary, K. J. Org. Chem. 2001, 66, 894-902.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/jo001387r |

2000

61. "An Efficient, General Asymmetric Synthesis of Carbocyclic Nucleosides: Application of an Asymmetric Aldol/Ring-Closing Metathesis Strategy" Crimmins, M. T.; King, B. W.; Zuercher, W. J.; Choy, A. L. J. Org. Chem. 2000, 65, 8499-8509.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/jo005535p |

60. "The Total Synthesis of (±)-Ginkgolide B" Crimmins, M. T.; Pace, J. M.; Nantermet, P. G.; Kim-Meade, A. S.; Thomas, J. B.; Watterson, S. H.; Wagman, A. S. J. Am. Chem. Soc. 2000, 122, 8453-8463.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja001747s |

59. "Diastereoselective Alkylations of Oxazolidinone Glycolates: A Useful Extension of the Evans Asymmetric Alkylation" Crimmins, M. T.; Emmitte, K. A.; Katz, J. D. Org. Lett. 2000, 2, 2165-2167.
| Full Article-PDF | DOI: 10.1021/ol006091m |

58. "An Efficient Strategy for the Synthesis of α,α'-cis and trans-Disubstituted Medium Ring Ethers" Crimmins, M. T.; Emmitte, K. A. Synthesis 2000, 6, 899-903.
| Full Article-PDF | DOI: 10.1055/s-2000-6268 |

57. "Total Synthesis of (+)-Prelaureatin and (+)-Laurallene" Crimmins, M. T.; Tabet, E. A. J. Am. Chem. Soc. 2000, 122, 5473-5476.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja0007197 |

56. "Solid-Phase Synthesis of Carbocyclic Nucleosides" Crimmins, M. T.; Zuercher, W. J. Org. Lett. 2000, 2, 1065-1067.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol005614n |

55. "Synthesis of the C16-C28 Spiroketal Subunit of Spongistatin 1 (Altohyrtin A): The Pyrone Approach" Crimmins, M. T.; Katz, J. D. Org. Lett. 2000, 2, 957-960.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol005605e |

54. "Titanium Enolates of Thiazolidinethione Chiral Auxiliaries: Versatile Tools for Asymmetric Aldol Additions" Crimmins, M. T.; Chaudhary, K. Org. Lett. 2000, 2, 775-777.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol9913901 |

53. "Synthesis of the C1-C13 Fragment of Leucascandrolide A" Crimmins, M. T.; Carroll, C. A.; King, B. W. Org. Lett. 2000, 2, 597-599.
| Full Article-PDF | DOI: 10.1021/ol991345t |

52. "Synthesis of Crossed [2 + 2] Photocycloadducts: A Novel Approach to the Synthesis of Bridged Bicyclic Alkenes" Crimmins, M. T.; Hauser, E. B. Org. Lett. 2000, 2, 281-284.
| Full Article-PDF | DOI: 10.1021/ol991272d |

51. "The Synthesis of 2-Alkyl-4-Pyrones from Meldrum's Acid" Crimmins, M. T.; Washburn, D. G.; Zawacki, F. J. Org. Synth. 2000, 77, 114.
| Full Article-PDF |

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1999

50. "Total Synthesis of (±)-Ginkgolide B" Crimmins, M. T; Pace, J. M.; Nantermet, P. G.; Kim-Meade, A. S.; Thomas, J. B.; Watterson, S. H.; Wagman, A. S. J. Am. Chem. Soc. 1999, 121, 10249-10250.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja993013p |

49. "An Asymmetric Aldol-Ring-Closing Metathesis Strategy for the Enantioselective Construction of Oxygen Heterocycles: An Efficient Approach to the Enantioselective Synthesis of (+)-Laurencin" Crimmins, M. T.; Choy, A. L. J. Am. Chem. Soc. 1999, 121, 5653-5660.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja990421k |

48. "Total Synthesis of (+)-Laurencin: An Asymmetric Alkylation-Ring-Closing Metathesis Approach to Medium Ring Ethers" Crimmins, M. T.; Emmitte, K. A. Org. Lett. 1999, 1, 2029-2032.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol991201e |

1998

47. "Asymmetric Total Synthesis of Callystatin A: Asymmetric Aldol Additions with Titanium Enolates of Acyloxazolidinethiones" Crimmins, M. T.; King, B. W. J. Am. Chem. Soc. 1998, 120, 9084-9085.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja9817500 |

46. "Synthesis of the AB Spiroketal Subunit of Spongistatin 1 (Altohyrtin A): The Pyrone Approach" Crimmins, M. T.; Washburn, D. G. Tetrahedron Lett. 1998, 39, 7487-7490.
| Full Article-PDF | DOI: 10.1016/S0040-4039(98)01629-3 |

45. "Pinacol-type Rearrangements of Intramolecular Photocycloadducts: Application of the 2,2-Dimethyl-4-pentenoate Protecting Group" Crimmins, M. T.; Carroll, C. A.; Wells, A. J. Tetrahedron Lett. 1998, 39, 7005-7008.
| Full Article-PDF | DOI: 10.1016/S0040-4039(98)01465-8 |

44. "An Improved Synthetic Preparation of 3-Butenal" Crimmins, M. T.; Kirincich, S. J.; Wells, A. J.; Choy, A. L. Synth. Comm. 1998, 28, 3675 - 3679.
| Full Article-PDF | DOI: 10.1080/00397919808004914 |

43. "New Developments in the Enantioselective Synthesis of Cyclopentyl Carbocyclic Nucleosides" Crimmins, M. T. Tetrahedron 1998, 54, 9299-9272.
| Full Article-PDF | DOI: 10.1016/S0040-4020(98)00320-2 |

42. "Addition of Metalated Pyrones to β-Alkoxy Aldehydes: Synthesis of Hydroxylated Spiroketals" Crimmins, M. T.; Washburn, D. G.; Katz, J. D.; Zawacki, F. J. Tetrahedron Lett. 1998, 39, 3439-3442.
| Full Article-PDF | DOI: 10.1016/S0040-4039(98)00566-8 |

41. "Double Diastereoselection in Intramolecular Photocycloadditions: A Radical Rearrangement Approach to the Total Synthesis of the Spirovetivane Phytoalexin (±)-Lubiminol" Crimmins, M. T.; Wang, Z.; McKerlie, L. A. J. Am. Chem. Soc. 1998, 120, 1747-1756.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja973824y |

1997

40. "Synthesis and Intramolecular Photocycloadditions of 2-Acyloxy-3-Hexenoyl Cyclohexenones: Diastereoselectivity in the Intramolecular [2 + 2] Photocycloadditions of Alkenes and Cyclohexenones Tethered by Four Atoms" Crimmins, M. T.; Watson, P. S.; King, B. W.; Guise, L. E. Tetrahedron 1997, 53, 8963-8974.
| Full Article-PDF | DOI: 10.1016/S0040-4020(97)90403-8 |

39. "An Asymmetric Aldol - Ring Closing Metathesis Strategy for the Enantioselective Construction of Six to Nine Membered Oxygen Heterocycles" Crimmins, M. T.; Choy, A. L. J. Org. Chem. 1997, 62, 7548-7549.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/jo9716688 |

38. "Solvent Effects on Diastereoselective Intramolecular [2 + 2] Photocycloadditions: Reversal of Selectivity through Intramolecular Hydrogen Bonding" Crimmins, M. T.; Choy, A. L. J. Am. Chem. Soc. 1997, 119, 10237-10238.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja9717119 |

37. "Asymmetric Aldol Additions with Titanium Enolates of Acyloxazolidinethiones: Dependence of Selectivity on Amine Base and Lewis Acid Stoichiometry" Crimmins, M. T.; King, B. W.; Tabet, E. A. J. Am. Chem. Soc. 1997, 119, 7883-7884.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja9716721 |

1996

36. "Asymmetric Total Synthesis of (+)-Milbemycin D" Crimmins, M. T.; Al-awar, R. S.; Vallin, I. M.; Hollis, W. G., Jr.; O'Mahony, R.; Lever, J. G.; Bankaitis-Davis, D. M. J. Am. Chem. Soc. 1996, 118, 7513-7528.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja961071u |

35. "An Efficient Asymmetric Approach to Carbocyclic Nucleosides: Asymmetric Synthesis of 1592U89, a Potent Inhibitor of HIV Reverse Transcriptase" Crimmins, M. T.; King, B. W. J. Org. Chem. 1996, 61, 4192-4193.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/jo960708p |

34. "Regioselective and Stereoselective Reductive Cleavage of 1,7-dioxaspiro[5.5]undecane Alcohols" Crimmins, M. T.; Rafferty, S. W. Tetrahedron Lett. 1996, 37, 5649-5652.
| Full Article-PDF | DOI: 10.1016/0040-4039(96)01196-3 |

33. "Radical Fragmentation of Cyclobutanes: An Approach to Medium Ring Fused Carbocycles" Crimmins, M. T.; Huang, S. J.; Guise-Zawacki, L. E. Tetrahedron Lett. 1996, 37, 6519-6522.
| Full Article-PDF | DOI: 10.1016/0040-4039(96)01433-5 |

32. "A Convenient Synthesis of Unsymmetrical, Substituted Pyrones from Meldrum's Acid" Zawacki, F. J.; Crimmins, M. T. Tetrahedron. Lett. 1996, 37, 6499-6502.
| Full Article-PDF | DOI: 10.1016/0040-4039(96)01470-0 |

31. "Rearrangement of Cyclobutylcarbinyl Radicals. The Total Synthesis of the Spirovetivane Phytoalexin, (±)-Lubiminol" Crimmins, M. T.; Wang, Z.; McKerlie, L. A. Tetrahedron Lett. 1996, 37, 8703-8706.
| Full Article-PDF | DOI: 10.1016/S0040-4039(96)02020-5 |

1995

30. "Addition of Functionalized Zinc Copper Reagents to Acetylenic Esters: Synthesis of 2-Carboalkoxy Cyclohexenones" Crimmins, M. T.; Guise, L. E.; Lacy, D. B.; Huang, S. J. Tetrahedron Lett. 1995, 36, 7061-7065.
| Full Article-PDF | DOI: 10.1016/0040-4039(95)01485-Z |

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1994

29. "Siloxanes as Temporary Tethers in [2 + 2] Photocycloadditions" Crimmins, M. T.; Guise, L. E. Tetrahedron Lett. 1994, 35, 1657-1660.
| Full Article-PDF | DOI: 10.1016/0040-4039(94)88312-2 |

1993

28. "Enone Olefin [2 + 2] Photochemical Cycloadditions" Crimmins, M. T.; Renihold, T. L. Organic Reactions 1993, 44, 297-588.
| DOI: 10.1002/0471264180.or044.02 |

27. "Synthetic Studies on the Ginkgolides: Total Synthesis of (±)-Bilobalide" Crimmins, M. T.; Gray, J. L.; Jung, D. K. J. Am. Chem. Soc. 1993, 115, 3146-3155.
| Full Article-PDF | DOI: 10.1021/ja00061a014 |

26. "Homoenolates and Other Functionalized Organometallics. A Review" Crimmins, M. T.; Nantermet, P. G. Org. Prep. & Proc. Int. 1993, 25, 41-81.

25. "Addition of Zinc Homoenolates to Acetylenic Esters and Amides: A Formal [3 + 2] Cycloaddition" Crimmins, M. T.; Nantermet, P. G.; Trotter, B. W.; Vallin, I. M.; Watson, P. S.; McKerlie, L. A.; Reinhold, T. L.; Cheung, A. W. H.; Stetson, K. A.; Dedopoulou, D.; Gray, J. L. J. Org. Chem. 1993, 58, 1038.
| Full Article-PDF | DOI: 10.1021/jo00057a013 |

24. "Stereoselective Intramolecular Enone-Olefin Photocycloadditions of 1,7-Dienes: Model Studies on the Synthesis of Lycopodium Alkaloids" Crimmins, M. T.; Watson, P. S. Tetrahedron Lett. 1993, 34, 199-202.
| Full Article-PDF | DOI: 10.1016/S0040-4039(00)60546-4 |

1992

23. "A Total Synthesis of (±)-Bilobalide" Crimmins, M. T.; Jung, D. K.; Gray, J. L. J. Am. Chem. Soc. 1992, 114, 5445-5447.
| Full Article-PDF | DOI: 10.1021/ja00039a077 |

22. "Cerium Chloride-Catalyzed Addition of Grignard Reagents to Vinylogous Esters: An Improved Route to 3-Substituted Cyclopent-2-en-1-ones" Crimmins, M. T.; Dedopoulou, D. Synth. Commun. 1992, 22, 1953-1958.
| DOI: 10.1080/00397919208021326 |

21. "A Fragmentation-Rearrangement Sequence of Cyclobutylcarbinyl Radicals" Crimmins, M. T.; Dudek, C. M.; Cheung, A. W.-H. Tetrahedron Lett. 1992, 33, 181.
| Full Article-PDF | DOI: 10.1016/0040-4039(92)88044-6 |

1990

20. "Synthesis of Spiroketals: A General Approach" Crimmins, M. T.; O'Mahony, R. J. Org. Chem. 1990, 55, 5894.
| Full Article-PDF | DOI: 10.1021/jo00310a023 |

19. "Addition of Zinc Homoenolates to Acetylenic Esters: A Formal [3 + 2] Cycloaddition" Crimmins, M. T.; Nantermet, P. G. J. Org. Chem. 1990, 55, 4235-4237.
| Full Article-PDF | DOI: 10.1021/jo00301a003 |

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1989

18. "A Synthesis of (-)-Talaromycin A" Crimmins, M. T.; O'Mahony, R. J. Org. Chem. 1989, 54, 1157.
| Full Article-PDF | DOI: 10.1021/jo00266a030 |

17. "Synthesis of the Spiroketal Fragment of Avermectin B1b" Crimmins, M. T.; O'Mahony, R. Tetrahedron Lett. 1989, 30, 5993.
| Full Article-PDF | DOI: 10.1016/S0040-4039(01)93836-5 |

16. "Intramolecular Enone-Furan Photocycloadditions; Studies toward the Synthesis of Ginkgolides A and B" Crimmins, M. T.; Thomas, J. B. Tetrahedron Lett. 1989, 30, 5997.
| Full Article-PDF | DOI: 10.1016/S0040-4039(01)93837-7 |

1988

15. "Studies Directed toward the Total Synthesis of the Minbemycins and Avermectins" Crimmins, M. T.; Hollis, W. G., Jr.; O'Mahony, R. Studies in Natural Products Chemistry 1988, 1, 435-495.

14. "Synthetic Applications of Intramolecular Enone-Olefin Photocycloadditions" Crimmins, M. T. Chem. Rev. 1988, 88, 1453-1473.
| Full Article-PDF | DOI: 10.1021/cr00090a002 |

13. "Total Synthesis of Milbemycin β3" Crimmins, M. T.; Bankaitis-Davis, D. M.; Hollis, W. G., Jr. J. Org. Chem. 1988, 53, 652-657.
| Full Article-PDF | DOI: 10.1021/jo00238a031 |

1987

12. "Intramolecular Photocycloaddition-Cyclobutane Fragmentation: Total Synthesis of (±)-Laurenene" Crimmins, M. T.; Bredon, L. D. J. Am. Chem Soc. 1987, 109, 6199.
| Full Article-PDF | DOI: 10.1021/ja00254a058 |

11. "Radical Cleavage of Cyclobutanes: Alternative Routes to (±)-Silphinene" Crimmins, M. T.; Mascarella, S. W. Tetrahedron Lett. 1987, 28, 5063.
| Full Article-PDF | DOI: 10.1016/S0040-4039(00)95590-4 |

10. "Studies Directed toward the Total Synthesis of the Milbemycins: Synthesis of the C11 to C31 Fragment of Milbemycin D" Crimmins, M. T.; Hollis, W. G., Jr.; Bankaitis-Davis, D. M. Tetrahedron Lett. 1987, 28, 3651-3654.
| Full Article-PDF | DOI: 10.1016/S0040-4039(00)96346-9 |

9. "Selenium Initiated Cyclization-[2,3]-Sigmatropic Rearrangement: Synthesis of the C1 to C10 Fragment of the Milbemycins and the Avermectins" Crimmins, M. T.; Lever, J. G.; Hollis, W. G., Jr. Tetrahedron Lett. 1987, 28, 3647.
| Full Article-PDF | DOI: 10.1016/S0040-4039(00)96345-7 |

1986

8. "Intramolecular Photocycloadditions-Cyclobutane Fragmentation: Total Synthesis of (±)-Pentalenene, (±)-Pentalenic Acid, and (±)-Deoxypentalenic Acid" Crimmins, M. T.; DeLoach, J. A. J. Am. Chem. Soc. 1986, 108, 800.
| Full Article-PDF | DOI: 10.1021/ja00264a037 |

7. "Intramolecular Photocycloadditions-Cyclobutane Fragmentation: Total Synthesis of (±)-Silphinene" Crimmins, M. T.; Mascarella, S. W. J. Am. Chem. Soc. 1986, 108, 3435.
| Full Article-PDF | DOI: 10.1021/ja00272a044 |

6. "Synthesis of the Hexahydrobenzofuran Subunit of the Milbemycins and the Avermectins" Crimmins, M. T.; Lever, J. G. Tetrahedron Lett. 1986, 108, 291-294.
| Full Article-PDF | DOI: 10.1016/S0040-4039(00)83999-4 |

1985

5. "Intramolecular Photocycloadditions: Synthesis of Sterically Congested Substituted [4.5.5.5] Fenestranes. Models for the Total Synthesis of Laurenene and Silphinene" Crimmins, M. T.; Mascarella, S. W.; Bredon, L. D. Tetrahedron Lett. 1985, 26, 997-1000.
| Full Article-PDF | DOI: 10.1016/S0040-4039(00)98495-8 |

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1984

4. "Conjugate Addition-Cycloacylation of Acetylenic Diesters: Synthesis of Highly Functionalized Cyclopentenones" Crimmins, M. T.; Mascarella, S. W.; DeLoach, J. A. J. Org. Chem. 1984, 49, 3033.
| Full Article-PDF | DOI: 10.1021/jo00190a037 |

3. "Intramolecular Photocycloaddition-cyclobutane Fragmentation: A Highly Stereoselective Total Synthesis of (±)-Pentalenic Acid" Crimmins, M. T.; DeLoach, J. A. J. Org. Chem. 1984, 49, 2076-2077.
| Full Article-PDF | DOI: 10.1021/jo00185a069 |

1983

2. "Synthesis of 2-Alkyl-2,3-dihydro-γ-Pyrones from 1-Methoxy-1-buten-3-yne" Crimmins, M. T.; Bankaitis, D. M. Tetrahedron Lett. 1983, 24, 5303-5304.
| Full Article-PDF | DOI: 10.1016/S0040-4039(00)87853-3 |

1. "Addition of 1-Methoxy-1-buten-3-yne to Lactones: Synthesis of Substituted Spiroketals" Crimmins, M. T.; Bankaitis, D. M. Tetrahedron Lett. 1983, 24, 4551-4554.
| Full Article-PDF | DOI: 10.1016/S0040-4039(00)85952-3 |