The Michael T. Crimmins Group Home Page


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103. "Total Synthesis of Irciniastatin A (Psymberin)" Crimmins, M. T.; Stevens, J. M.; Schaaf, G. M. Org. Lett. 2009, 11, 3990-3993.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol901655e |

102. "Enantioselective Total Synthesis of Brevetoxin A: Convergent Coupling Strategy and Completion" Crimmins, M. T.; Zuccarello, J. L.; McDougall, P. J.; Ellis, J. M. Chem. Eur. J. 2009, 15, 9235-9244.
| Full Article-PDF | (Supporting Information) | DOI: 10.1002/chem.200900777 |

101. "Enantioselective Total Synthesis of Brevetoxin A: Unified Strategy for the B, E, G, and J Subunits" Crimmins, M. T.; Ellis, J. M.; Emmitte, K. A.; Haile, P. A.; McDougall, P. J.; Parrish, J. D.; Zuccarello, J. L. Chem. Eur. J. 2009, 15, 9223-9234.
| Full Article-PDF | (Supporting Information) | DOI: 10.1002/chem.200900776 |

100. "Asymmetric Total Synthesis of Pyranicin" Crimmins, M. T.; Jacobs, D. L. Org. Lett. 2009, 11, 2695-2698.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol900814w |

99. "Enantioselective Total Synthesis of (-)-Pironetin: Iterative Aldol Reactions of Thiazolidinethiones" Crimmins, M. T.; Dechert, A.-M. R. Org. Lett. 2009, 11, 1635-1638.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol9003228 |

98. "Total Synthesis of Apoptolidin A" Crimmins, M. T.; Christie, H. S.; Long, A.; and Chaudhary, K. Org. Lett. 2009, 11, 831-834.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol802829n |

97. "Total Synthesis of Brevetoxin A" Crimmins, M. T.; Zuccarello, J. L.; Ellis, J. M.; McDougall, P. J.; Haile, P. A.; Parrish, J. D.; Emmitte, K. A. Org. Lett. 2009, 11, 489-492.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol802710u |

95. "An Intramolecular Diels-Alder Strategy for the Asbestinins: Enantioselective Total Syntheses of 11-Acetoxy-4-deoxyasbestinin D and Asbestinin-12" Crimmins, M. T.; Ellis, J. M. J. Org. Chem. 2008, 73, 1649-1660.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/jo0712695 |

91. "Enantioselective Total Synthesis of (+)-SCH 351448" Crimmins, M. T.; Vanier, G. S. Org. Lett. 2006, 8, 2887-2890.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol061073b |

90. "Total Synthesis of (-)-Mucocin" Crimmins, M. T.; Zhang, Y.; Diaz, F. A. Org. Lett. 2006, 8, 2369-2372.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol060704z |

89. "Formal Synthesis of 6-Deoxyerythronolide B" Crimmins, M. T.; Slade, D. J. Org. Lett. 2006, 8, 2191-2194.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol0607241 |

88. "Enantioselective Total Synthesis of Bistramide A" Crimmins, M. T.; DeBaillie, A. C. J. Am. Chem. Soc. 2006, 128, 4936-4937.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja057686l |

87. "Enantioselective Total Synthesis of FD-891" Crimmins, M. T.; Caussanel, F. J. Am. Chem. Soc. 2006, 128, 3128-3129.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja060018v |

85. "An Intramolecular Diels-Alder Approach to the Eunicellins: Enantioselective Total Syntheses of Ophirin B and Astrogorgin" Crimmins, M. T.; Brown, B. H.; Plake, H. R. J. Am. Chem. Soc. 2006, 128, 1371-1378.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja056334b |

83. "Establishing the Absolute Configuration of the Asbestinins: Enantioselective Total Synthesis of 11-Acetoxy-4-deoxyasbestinin D" Crimmins, M. T.; Ellis, J. M. J. Am. Chem. Soc. 2005, 127, 17200-17201.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja056921x |

82. "Enantioselective Synthesis of Apoptolidinone: Exploiting the Versatility of Thiazolidinethione Chiral Auxiliaries" Crimmins, M. T.; Christie, H. S.; Chaudhary, K.; Long, A. J. Am. Chem. Soc. 2005, 127, 13810-13812.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja0549289 |

79. "Enantioselective Total Synthesis of (+)-Gigantecin: Exploiting the Asymmetric Glycolate Aldol Reaction" Crimmins, M. T.; She, J. J. Am. Chem. Soc. 2004, 126, 12790-12791.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja0455852 |

78. "An Intramolecular Diels-Alder Approach to the Eunicelins: Enantioselective Total Synthesis of Ophirin B" Crimmins, M. T.; Brown, B. H. J. Am. Chem. Soc. 2004, 126, 10264-10266.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja046574b |

74. "Enantioselective Total Synthesis of (+)-Leucascandrolide A Macrolactone" Crimmins, M. T.; Siliphaivanh, P. Org. Lett. 2003, 5, 4641-4644.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol035797o |

73. "Enantioselective Total Synthesis of (+)-Rogioloxepane A" Crimmins, M. T.; DeBaillie, A. C. Org. Lett. 2003, 5, 3009-3011.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol034923l |

72. "Enantioselective Total Synthesis of (+)-Obtusenyne" Crimmins, M. T.; Powell, M. T. J. Am. Chem. Soc. 2003, 125, 7592-7595.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja029956v |

70. "Asymmetric Total Synthesis of (-)-Laulimalide: Exploiting the Asymmetric Glycolate Alkylation Reaction" Crimmins, M. T.; Stanton, M. G.; Allwein, S. P. J. Am. Chem. Soc. 2002, 124, 5958-5959.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja026269v |

69. "Asymmetric Total Synthesis of Spongistatins 1 and 2" Crimmins, M. T.; Katz, J. D.; Washburn, D. G.; Allwein, S. P.; McAtee, L. F. J. Am. Chem. Soc. 2002, 124, 5661-5663.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja0262683 |

68. "Ring Closing Metathesis for the Formation of Medium Ring Ethers: The Total Synthesis of (-)-Isolaurallene" Crimmins, M. T.; Emmitte, K. A.; Choy, A. L. Tetrahedron 2002, 58, 1817-1834.
| Full Article-PDF | DOI: 10.1016/S0040-4020(02)00040-6 |

65. "Formal Total Synthesis of (+)-Trehazolin. Application of an Asymmetric Aldol-Olefin Metathesis Approach to the Synthesis of Functionalized Cyclopentenes" Crimmins, M. T.; Tabet, E. A. J. Org. Chem. 2001, 66, 4012-4018.
| Full Article-PDF | DOI: 10.1021/jo015568k |

63. "Asymmetric Total Synthesis of (-)-Isolaurallene" Crimmins, M. T.; Emmitte, K. A. J. Am. Chem. Soc. 2001, 123, 1533-1534.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja005892h |

60. "The Total Synthesis of (±)-Ginkgolide B" Crimmins, M. T.; Pace, J. M.; Nantermet, P. G.; Kim-Meade, A. S.; Thomas, J. B.; Watterson, S. H.; Wagman, A. S. J. Am. Chem. Soc. 2000, 122, 8453-8463.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja001747s |

57. "Total Synthesis of (+)-Prelaureatin and (+)-Laurallene" Crimmins, M. T.; Tabet, E. A. J. Am. Chem. Soc. 2000, 122, 5473-5476.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja0007197 |

50. "Total Synthesis of (±)-Ginkgolide B" Crimmins, M. T; Pace, J. M.; Nantermet, P. G.; Kim-Meade, A. S.; Thomas, J. B.; Watterson, S. H.; Wagman, A. S. J. Am. Chem. Soc. 1999, 121, 10249-10250.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja993013p |

49. "An Asymmetric Aldol-Ring-Closing Metathesis Strategy for the Enantioselective Construction of Oxygen Heterocycles: An Efficient Approach to the Enantioselective Synthesis of (+)-Laurencin" Crimmins, M. T.; Choy, A. L. J. Am. Chem. Soc. 1999, 121, 5653-5660.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja990421k |

48. "Total Synthesis of (+)-Laurencin: An Asymmetric Alkylation-Ring-Closing Metathesis Approach to Medium Ring Ethers" Crimmins, M. T.; Emmitte, K. A. Org. Lett. 1999, 1, 2029-2032.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ol991201e |

47. "Asymmetric Total Synthesis of Callystatin A: Asymmetric Aldol Additions with Titanium Enolates of Acyloxazolidinethiones" Crimmins, M. T.; King, B. W. J. Am. Chem. Soc. 1998, 120, 9084-9085.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja9817500 |

41. "Double Diastereoselection in Intramolecular Photocycloadditions: A Radical Rearrangement Approach to the Total Synthesis of the Spirovetivane Phytoalexin (±)-Lubiminol" Crimmins, M. T.; Wang, Z.; McKerlie, L. A. J. Am. Chem. Soc. 1998, 120, 1747-1756.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja973824y |

36. "Asymmetric Total Synthesis of (+)-Milbemycin D" Crimmins, M. T.; Al-awar, R. S.; Vallin, I. M.; Hollis, W. G., Jr.; O'Mahony, R.; Lever, J. G.; Bankaitis-Davis, D. M. J. Am. Chem. Soc. 1996, 118, 7513-7528.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/ja961071u |

35. "An Efficient Asymmetric Approach to Carbocyclic Nucleosides: Asymmetric Synthesis of 1592U89, a Potent Inhibitor of HIV Reverse Transcriptase" Crimmins, M. T.; King, B. W. J. Org. Chem. 1996, 61, 4192-4193.
| Full Article-PDF | (Supporting Information) | DOI: 10.1021/jo960708p |

31. "Rearrangement of Cyclobutylcarbinyl Radicals. The Total Synthesis of the Spirovetivane Phytoalexin, (±)-Lubiminol" Crimmins, M. T.; Wang, Z.; McKerlie, L. A. Tetrahedron Lett. 1996, 37, 8703-8706.
| Full Article-PDF | DOI: 10.1016/S0040-4039(96)02020-5 |

27. "Synthetic Studies on the Ginkgolides: Total Synthesis of (±)-Bilobalide" Crimmins, M. T.; Gray, J. L.; Jung, D. K. J. Am. Chem. Soc. 1993, 115, 3146-3155.
| Full Article-PDF | DOI: 10.1021/ja00061a014 |

23. "A Total Synthesis of (±)-Bilobalide" Crimmins, M. T.; Jung, D. K.; Gray, J. L. J. Am. Chem. Soc. 1992, 114, 5445-5447.
| Full Article-PDF | DOI: 10.1021/ja00039a077 |

18. "A Synthesis of (-)-Talaromycin A" Crimmins, M. T.; O'Mahony, R. J. Org. Chem. 1989, 54, 1157.
| Full Article-PDF | DOI: 10.1021/jo00266a030 |

13. "Total Synthesis of Milbemycin β3" Crimmins, M. T.; Bankaitis-Davis, D. M.; Hollis, W. G., Jr. J. Org. Chem. 1988, 53, 652-657.
| Full Article-PDF | DOI: 10.1021/jo00238a031 |

12. "Intramolecular Photocycloaddition-Cyclobutane Fragmentation: Total Synthesis of (±)-Laurenene" Crimmins, M. T.; Bredon, L. D. J. Am. Chem Soc. 1987, 109, 6199.
| Full Article-PDF | DOI: 10.1021/ja00254a058 |

11. "Radical Cleavage of Cyclobutanes: Alternative Routes to (±)-Silphinene" Crimmins, M. T.; Mascarella, S. W. Tetrahedron Lett. 1987, 28, 5063.
| Full Article-PDF | DOI: 10.1016/S0040-4039(00)95590-4 |

8. "Intramolecular Photocycloadditions-Cyclobutane Fragmentation: Total Synthesis of (±)-Pentalenene, (±)-Pentalenic Acid, and (±)-Deoxypentalenic Acid" Crimmins, M. T.; DeLoach, J. A. J. Am. Chem. Soc. 1986, 108, 800.
| Full Article-PDF | DOI: 10.1021/ja00264a037 |

7. "Intramolecular Photocycloadditions-Cyclobutane Fragmentation: Total Synthesis of (±)-Silphinene" Crimmins, M. T.; Mascarella, S. W. J. Am. Chem. Soc. 1986, 108, 3435.
| Full Article-PDF | DOI: 10.1021/ja00272a044 |

3. "Intramolecular Photocycloaddition-cyclobutane Fragmentation: A Highly Stereoselective Total Synthesis of (±)-Pentalenic Acid" Crimmins, M. T.; DeLoach, J. A. J. Org. Chem. 1984, 49, 2076-2077.
| Full Article-PDF | DOI: 10.1021/jo00185a069 |