Online archives for the Undergraduate Bulletin, beginning fall 1997 and forward, are available here.
Undergraduate Bulletins (dating from 1922) are housed at the Undergraduate Library; University of North Carolina catalogues prior to 1922 are available in the North Carolina Collection, Wilson Library.
For all offical transcripts you will need to contact the Office of the University Registrar.
Included below are various documents and reports related to the pre-2006 undergraduate Perspectives Curriculum.
Administrative Boards of the General College and College of Arts and Sciences: Agendas and Minutes
Other documents available upon request.